Wood is a material often used by architects to enhance the overall ambience of a space, but few researches have been reported to discuss its actual impact on visual impression and luminous effects. This research studies the influence of wood materiality in relation to creating specific lighting ambiances in architecture. In particular, it focuses on the impact of decorative wood indoor panels on the creation of daylighting diversity in interior space and the potential to improve daylighting quality and energy efficiency. The research uses scaled models for their accuracy in rendering complex daylighting ambiances. The photo-luminance meter enables the comparison between different settings of interior spaces created by a selection of wood type materiality: ratio (percentage), colour (Oak, Cape Cod Grey and Dark Walnut coatings) and gloss concerning illuminance patterns obtained from Ecotect software. The CIE L*a*b* colour space is used to classify luminous ambiances. Results indicate that bright colour Oak favours a deeper daylighting penetration and increases the colour temperature of the space by about 300% when applied on the floor. Cape Cod Grey coating provided a neutral colour balance even under sunlighting. High gloss Dark Walnut located on the ceiling produces the highest luminance values, enlarging the window-lighting pattern. The research underlines the role of wood materiality in achieving luminous diversity and creating visually comfortable interior ambiances.